Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.Sodium formate is used in several fabric dying and printing processes. It is also used as a buffering agent for strong mineral acids to increase their pH.

Preparation

Sodium formate can be prepared in the laboratory by neutralizing formic acid with sodium carbonate. It can also be obtained by reacting chloroform with an alcoholic solution of sodium hydroxide.

CHCl₃ + 4NaOH → HCOONa + 3NaCl + 2H₂O

or by reacting sodium hydroxide with chloral hydrate.

C₂HCl₃(OH)₂ + NaOH → CHCl₃ + HCOONa + H₂O

The latter method is generally preferred to the former because the low aqueous solubility of CHCl₃ makes it easier to separate out from the sodium formate solution, by fractional crystallization, than the soluble NaCl would be.